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Synthesis of alkyl azides. Recent ... Azide transfer of 2-azido-1,3 ... to alcohols proceeds to give the corresponding azides under mild reaction ...

The Schmidt reaction is the reaction of hydrazoic acid or an alkyl azide with a carbonyl compound, alkene, or alcohol, often in the presence of a Brønsted or Lewis acid.

and N -alkyl-substituted anilines, [9] as well as precursors for ... substitution reactions the azide group acts as an ortho - and para -directing substituent.

Schmidt Rearrangement Reactions with Alkyl Azides 193 shown). However, hindsight helped workers nearly fi fty years later 14 to formulate a more